The Topographic map (from SRTM), digital elevation model (from SRTM), geology & geomorphology map (from GSI), drainage map (from toposheet, DEM), Stream order map, land use land cover map (from LISS-III, 2017), Thiessen polygon map (from rain gauge stations) were prepared and used as layers in integrated flow modelling.
Demarcation of various quarries, old channels in Chennai region were carried out with Satellite imagery and toposheets and possible interventions were noted based on the base maps prepared in ArcGIS 10.4 software package.
Volume of the quarries, water availability in quarries and water bodies, surface and groundwater level in different locations and elevations were assessed, thus possible links and diversions were conceptualized.
Rainfall occurrence and variation studies for the Adyar sub-basin for the past 39 years were analyzed using the homogeneous and autocorrelated rainfall records procured from IMD and PWD.
a box-model approach for reservoir operation (Chembarambakkam reservoir) under extreme conditions has been developed and the performance was ascertained using the correlation coefficient and Nash–Sutcliffe efficiency with an average error estimation of 15% and 25% in water level, 21% and 18% in outflow simulation, respectively.
The R-R model for the Chembarambakkam sub-catchment was set up using MIKE11 NAM package and the performance of this model was ascertained using the Coefficient of determination and water balance error with 0.72 and -10% respectively.
The Chembarambakkam reservoir (3.65 TMC) and the three abandoned quarries (1 TMC approx.) at the downstream part of the modelled Chembarambakkam sub-catchment were used for distributing and storing the simulated discharge to achieve improved water storage, reduced inundation and better water supply.
The flow model of Adyar watershed using MIKESHE package has been set up. Calibration and validation are in progress.
The daily rainfall data, projected under RCP 4.5 and 8.5 from RegCM 4.4 prepared by IITM, Pune was acquired for the Chennai region and was downscaled and bias-corrected by linear scaling method using IMD daily rainfall data. The projected rainfall data until 2100 will be used for further simulations of the model.
The water samples from abandoned quarries, lakes, ponds and groundwater were collected and analyzed periodically once in three months
Collection of real time data of river discharges at critical locations across Adyar River and Kosasthalaiyar River.
Evaluation of the hydrological response of the catchment due to the application of different combinations of SUDS using SWMM.
Vadose zone modelling using HYDRUS -1D to simulate the infiltration based SUDS to combat the limitations of SWMM in SUDS representation through SWMM-HYDRUS coupling.
Development of the SWMM-HYDRUS-1D coupled model using pySWMM and phydrus to simulate hydrological response of rainwater harvesting, permeable pavement, infiltration trench, infiltration basin and recharge shaft for IIT Madras campus, India.
Formulation of methodology for strategizing a regional level planning of SUDS that would facilitate holistic water resource management for the basin.
Development of modules for SWAT model formulation of LIDs using MATLAB to facilitate river basin scale decision making.
LID modules for bio-retention cells, rain gardens, green roofs, permeable pavements, infiltration trenches and swales were formulated and the verification of the same is going on using HYDRUS 1D model.
Conceptual model for recharge shaft was formulated and the development of the module is completed.
Hydrological and hydraulic modelling to estimate the impact of traditional water storage tanks to control flood inundations in the Pallikaranai Marshland.
Data sets that represent critical watershed parameters for site suitability analysis of LID components were collected from various sources.
Methodology for site suitability analysis of LID components using Multi-Criteria approach was formulated.
Thematic data layers viz., depth to bedrock, drainage density, geology, geomorphology, land use & land cover, lineament density, profile curvature, rainfall, slope, soil, Topographic Position Index (TPI), and Topographic Wetness Index (TWI) was created in GIS.
Preliminary site suitability map of detention basin using Analytical Hierarchy Process (AHP) was prepared for Chennai basin using 11 of 14 thematic layers.
Collection of rainfall data and calibration of time series predictive model developed at the study areas, and tracking the change in trend, cyclicity and seasonality
Spatio-temporal hydrological modeling at University campus and estimation of water quality contours
Assessment of water flow pattern variation through SWAT modeling and exploration of improved water utilization approach.
WP2:-Water Treatment
Development of portable and low-cost techniques for detecting and removing trace pollutants. For this, a traditional method such as paper strip sensor and carbon-based adsorbents from waste have been tested. At the same time, two low-cost green adsorbents were made from agriculture and sewage sludge to remove emerging contaminants. A risk assessment model was developed to characterize the hazard efficiency of micropollutants in the Cauvery river basin. Additionally, the application of MOF for sorptive and electrosorption removal of phosphate was teste
Degradation of three dyes (methylene blue, methyl orange and basic fuchsin) was studied in pulse power plasma technology was completed
To utilize the pulse in activation of catalyst was studied to improve the efficiency of technology and to reduce the cost of the treatment process
Effects of various parameters such as input voltage, initial dye concentration, treatment time etc was studied to find the optimized treatment condition
The degradation mechanism and cost of treatment is being carried out to understand the feasibility of such process in dye degradation
The synthesis of triptycene based polymers was completed to use for sorptive removal of pharmaceuticals (diclofenac and carbamazepine) from wastewater
Adsorption studies and the effect of ultrasonication is being studied
The model-based analysis will be carried out to optimize the various parameters involved
Characterization of the polymers is carried out to find out the mechanism behind the sorption
Nanocellulose reinforced organo-inorganic nanocomposite for synergistic and affordable defluoridation of water and an evaluation of its sustainability metrics
Sensors and Kits for Water Quality Monitoring
Scalable drop-to-film condensation on a nanostructured hierarchical surface for enhanced humidity harvesting
The properties of the electrochemical cell (adopted with three-electrode configuration) was measured by Electrochemical impedance spectroscopy (EIS) and cyclic voltammogram (CV). This work is in progress now
A Covalently Integrated Reduced Graphene Oxide–Ion-Exchange Resin Electrode for Efficient Capacitive Deionization
Industrial Utilization of Capacitive Deionization Technology for the Removal of Fluoride and Toxic Metal Ions (As3+/5+ and Pb2+)
Low-cost microfluidic platform for multi-analyte assessment of water quality
The standalone AgNC film showed good stability in water, and the system could release silver ions of the required quantity till 500 cycles in distilled water and 250 cycles in surface and groundwater
The AgNC films subjected to various water conditions were investigated with microscopic and spectroscopic tools
The spent AgNC films were recycled to form composite termed as "G Plug," and it is disposed of as a sealant to heal micro-cracks in the concrete
The G Plug has demonstrated excellent potential to seal the micro-cracks in the concrete and enhanced the compressive strength of the concrete cubes that are subjected to damage
The interaction between G Plug and the cement were studied using spectroscopic and microscopic characterization tools
The concrete cubes sealed with G plug was evaluated for the potential leaching of Ag ions via modified TCLP analysis, and the results showed that the release of Ag ions is around 150 times lesser than the permissible limits given by RCRA
Based on the results, a manuscript titled "Chitosan-based nanopolymer composite as a sustainable point-of-use reservoir of silver ions: Water disinfection and safe disposal" is being prepared
Methods of coating nanocomposite film on various surfaces for developing a PoU system were studied. Among various methods, (i) coating on a glass substrate after pretreatment at high temperature and pressure in the presence of Tri-sodium citrate and (ii) packed bed reactor employing nanocomposite beads were found to be feasible
The coating of nanocomposite coated citrate-functionalized glass plates is found to be hydraulically stable
The studies showed approximately 100% removal of U(VI) [5 mg/L]. Isotherm studies showed a maximum adsorption capacity of 183 mg/g at 30 oC
An article titled "A critical review of uranium contamination in groundwater bodies: Treatment and safe disposal" is accepted with minor revisions in the Journal Science of Total Environment
Article titled "Chitosan immobilized granular FeOOH-MnXOY bimetal-oxides nanocomposites for the adsorptive removal of lead from water" is accepted with minor revisions in the Journal of Environmental and Chemical Engineering
The electronic components are procured locally and assembled. The instrument comprises of linear voltage regulator powered by a 12V battery, which has been fed into the switching voltage converted to 5V. This is to provide the differential voltage at the potentiostatic unit. An integrated circuit LM2902N has been used to connect the three electrode system comprises of working, counter, and reference electrode. An LED display is also integrated into the device, which indicates the changes in the potential and has been proportional to the concentration of metal ions present in the system. The electrode was constructed using the carbohydrazide and thymine functionalized graphene oxide drop cast on the screen-printed carbon electrode surface. Further, fabricated electrodes were used for the electrochemical sensor using the handheld device developed by us. Initially, the electrode was validated for sensing using the electrochemical workstation. The fabricated handheld device was evaluated for sensing chromium(VI) and control samples. The electrode senses the metal ions by indicating the potential changes corresponding to the specific metal ion. This handheld electrochemical device can use for on-site detection of chromium (VI) in an environmental water sample. Further, evaluation of the device is in progress and the total materials cost of the device is around Rs.1000/-.
Graphene oxide (GO) synthesized as a building block for the reporter and grafted are L-Cysteine functionalization. The grafted and graphene oxide are connected covalently via C-S conjugation. The solid-state nuclear resonance spectroscopy (ss-NMR) data shows the functionalization of graphene oxides (Figure 1). It confirms the attachment of L-cysteine on the graphene oxide layer. Further evaluation of the materials for sensing is in progress. Sample
Control.
For colorimetric sensing, the following molecules were synthesized, characterized and the sensing studies are being evaluated.
The toxicity studies of the synthesized compounds were evaluated using MTT assay.
Human skin origin, HaCaT and Kera cell lines as well as A549 and MCF 7 cancer cell lines were used for the study.
Fabrication conditions for molecular cage derived crystalline covalent organic framework based free-standing film for nanofiltration.
The recent research findings on broad-spectrum micropollutant removal from water published in ACS Appl. Mater. Interfaces has been shared with the media team. The news is going to be covered with frontline print media.
Testing of pristine and sulfonated HCPs for real-time removal of pharmaceuticals found in Indian surface water in collaboration with Prof. Ligy Philip Group, IITM
We have successfully developed a simple, greener, and cost-effective way to synthesize 2D and 3D GBM from the extract and fibre of Drepanostachyum falcatum. At low temperatures (150 °C), the 2D-MDGOs are extremely hydrophilic and readily bluish fluorescent under UV light of 365 nm. This material is biocompatible and nontoxic, whereas the synthesized 3D-GNR at high temperature (300 °C) is hydrophobic and has a 3D network-like structure. This 3D-GNR shows its excellent behavior for the removal of cationic dyes, i.e., MB. Therefore, the 3D-GNR can act as a promising candidate in the field of water purification.
We have submitted the manuscript titled "Green and cost-effective synthesis of 2D and 3D Graphene-based nanomaterials from Drepanostachyum falcatum for Bio-imaging and Water purification applications" to a reputed journal, "Chemical Engineering Journal Advances." The manuscript is under revision.
In addition, in this time frame, we successfully synthesized graphene-based sponge for oil water separation, and manuscript has been submitted.
We have successfully developed nanocomposites using agricultural waste and waste plastic derived graphene. The synthesized materials have been characterized by Raman, XRD, FTIR, UV, and TGA. Some characterization and lead removal studies are in progress.
Also in this frame of time, we developed the material for graphene-based water filters. The synthesis of the material has been completed and the testing of the water filter made from our sample is in progress.
WP3:-Wastewater Management
In this study, the fate of three PhACs – atenolol (ATL),
carbamazepine (CBZ), and diclofenac (DCF) were investigated in each component
of the CW.
The hydroponics study with Canna
indica removed 19.3 to 31.2% without
substrate materials (initial PhACs:100 µg/L each).
The breakthrough and sorption capacity of unplanted CW
followed the order: natural zeolite (1.6-2.15µg/g) < Light-weight expanded
clay aggregate (LECA) (5.37-8.27µg/g) < waste autoclaved aerated concrete
(AAC) block (9.27-10.79µg/g) < wood charcoal (24.1-26.4µg/g), according to
their surface and textural properties.
Eventually, four laboratory-scale CW units with
enriched microbes, C. indica, and different supporting materials
were monitored for the removal of organics, nutrients, and PhACs.
The synergistic interaction among AAC blocks, macrophytes,
and microbial population in the system exhibited higher removal of COD, TN, TP,
and PhACs as 88.6%, 81.6%, 77.6%, and 95.3%, respectively.
Owing to the highly porous nature of waste AAC blocks,
higher microbial activity was observed in the CW unit with AAC as substrate
material.
Performance of pilot scale ceramic membrane filter with pore
size of 4 µm was tested for treating secondary treated wastewater under
different operating conditions.
Study showed that the filter was able to achieve desired
treated wastewater quality with respect to pH, Turbidity, COD and Fecal
coliforms.
Removal efficiency of different pollutants such as turbidity,
TSS, COD, and Fecal coliform ranged between 94-98.5%, 86-100%, 45-60%, and
80-85% respectively for 4µm pilot scale ceramic filter.
Batch process was carried out to check the efficiency of
filter by fixing the flow rate below 15m3/h till the pressure reaches 1.5 bar.
For every cycle, the flux value has been calculated by using
volume of water filled in the permeate tank w.r.t time and the Transmembrane
pressure evolve during each cycle.
Air + water Backwash was initiated at the end of each cycle.
The provision of air + water backwash was able to recover the original flux
during each cycle of operation.
After modification work for continuous process, Flux
Monitoring study has been carried out by fixing flowrate below 15m3/h for
continuous process.
Air + water Backwash was initiated for 30sec at the end of
each cycle and the volume along with percentage of water used for backwash also
estimated for every cycle.
Optimization of running time by 20 minutes and 25 minutes
was carried out for every cycle and flux also calculated.
Chemical backwash was found to be effective in flux recovery
Chemical washing was initiated to clear the blockage due to fouling when the
transmembrane pressure not reduced as much after the air + water backwash.
Chemical backwash was initiated in an efficient way by
combining Caustic and hypochlorite and found to be effective.
Overall cumulative net treated water and backwash water
volume for 90 cycles was 2,53,718 L and 11,240 L, respectively. Percentage of
water used for backwash was found to be below 5.
Overall studies showed that the treated wastewater quality
from ceramic filter (CF) was as same as the existing ultrafiltration (UF)
outlet in IITM STP.
The feasibility of decolorization of high concentration of
azo dye Methyl Red (MR) in the presence of sucrose and NO3--N was evaluated in
a laboratory scale membrane bioreactor operated in sequencing batch mode.
Mixed microbial culture, which was previously enriched in a
simple sequencing batch reactor under anoxic and static conditions, was used as
seed biomass to decolorize high concentrations of MR (500 mg/L) using NO3--N as
electron acceptor during start-up.
After successful start-up, the reactor performance was
assessed in increasing loading rates by decreasing the Hydraulic Retention Time
(HRT) in different phases of reactor operation.
Results indicate an effective decolorization of MR. Maximum
removals of color (93%), COD (85%), and TN (81%) were achieved in phase I at a
HRT of 16 d. On increasing the loading rate, the average removals obtained in
phase III at a HRT of 4 d were color (77%), COD (78%), TOC (76%), and TN (95%).
This process may help in treating dye effluents cost-effectively using hybrid
technologies (biological treatment followed other advanced techniques) because
around 75% of dye could be treated in anoxic conditions without external
aeration.
A review paper published based on nutrients recovery from
wastewater to promote circular economy and sustainable agricultural practice in
India·
A book chapter
(Springer) published titled ‘Hybrid Bioreactors for Dye Biodegradation’.
A mini review paper published based on preliminary results
of bio solids management using nano-scale oxides of Iron
.
Fine tuning AD-MEC unit and optimization of nitrogen flow
rate as well as recirculation ratio (and flow rate)
Estimation of energy harvesting and water quality
purification potential of the MFC/MEC system along with accompanying efficient
sludge utilization approach
Inoculum development (SBR) – Development of bacterial
consortia for the removal of carbon and nitrogen removal in Sequential batch
reactor.
Batch
studies were performed to evaluate the efficiency of bacterial consortia.
After acclimatization process, Sequential batch process was
performed to study the efficiency of inoculum for the aerobic process (C &
N removal) with the cycle time of 36 and 24 hrs was evaluated over a period of
240 days.
Inoculum development (UASB) – Cultivation and enrichment of
sulfur reducing bacteria (SRB) using three different medium
The acclimatization of bacterial consortium for the removal
of Sulphur and Nitrate and residual COD from the synthetic tannery wastewater.
The initial concentration of COD in UASB was 830 (±165) mg/L
which got reduced to 270 (±80) mg/L. The maximum removal efficiency of Sulphate
was found to be 58.8 % with the initial concentration of 1028 (±86) mg/L and
the sulphide concentration in the final effluent was 315 (± 58) mg/L.
The performance of the SBR for three different COD of
loading rates (1.36, 1.85, and 2.45) has been evaluated.
SBR Kinetic studies has been performed to find the complete
cycle and its treatment efficiency.
Degradation kinetics were performed based on the
experimental data obtained from SBR and found that Monod and first order model
fits well.
The
performance of the SBR for four different nitrogen of loading rates (0.101,
0.145, 0.178, 0.237 g/L/d) has been evaluated over a period of 30 days at each
loading rate and TKN removal efficiencies were found to be 83.3, 87.7, 83.3 and
80.9 respectively.
Gene amplification was performed in the Bacterial sludge
from SBR and confirmed the presence of ammonia oxidizing and nitrifying
bacteria using PCR.
Preliminary studies with Combined De-Sulfurization,
De-nitrification and conversion of sulphide into elemental sulfur showed
enhanced performance in the UASB with microaerophilic process.
WP4:-Collection and distribution
Model based operation of water networks require a well calibrated model. Using available data (flow, pressure, heights of water in tanks), a nonlinear least squares problem is formulated to estimate the network parameters.
Network parameters are guessed in an outer loop while the hydraulic simulation is carried out in the inner loop.
Model based scheduling of water distribution networks results in a nonlinear mixed integer optimization problem.
In the past, we have reformulated the same as an integer linear program improving the tractability of the problem. We
have developed heuristics to improve the solution times considerably.
A web based application will be released for public use shortly.
We have also developed pure data driven techniques for scheduling which use only flow data and require no network or hydraulic model.
This has been validated on a 9 tank system in the IIT Madras laboratory network using discrete valves and 4 tank system using continuous control valves.
We have formulated and demonstrated a methodology for reconstrucitng a putative water network from street network.
Openstreetmap data of Chennai city from openstreetmaps was used to extract the network and connectivity structure of the road/street along with additional useful and relevant information (eg., type of structure- residential/commercial etc.) Appropriate graph algorithms (eg., shortest path tree/minimum spanning tree) were used to generate candidate network structures for the WDN.